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Jeneng Produk: |
Ketone kasturi |
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Sinonim: |
2-Acetyl-5-tert-butyl-4,6-dinitro-1,3-dimethylbenzene; 3 ', 5'-Dinitro-4'-tert-butyl-2', 6'-dimethylacetophenone; 3, 5-Dinitro -4-t-butyl-2, 6-dimethylacetophenone; KetoneMoschus, 4-tert-Butyl-2,6-dimethyl-3,5-dinitroacetophenone, Musk ketone; Muskketone, 4-tert-Butyl-2,6-dimethyl- 3,5-dinitroacetophenone, Ketone Moschus; Musone ketone 0; SyntheticMusk ketone; 4â € ™ -tert-butyl-2â € ™, 6â -dimethyl-3â € ™, 5â -dinitro-acetophenon |
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CAS: |
81-14-1 |
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MF: |
C14H18N2O5 |
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MW: |
294.3 |
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EINECS: |
201-328-9 |
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Kategori Produk: |
Kosmetik; TAMBAHAN TAMBAHAN & Panganan; Acetophenones & Derivatif Aromatik (diganti); Organik; KetonAlfabet; Standar Analitis; Standar AromatikAnalitik; Kelas Kimia; Standar Ilmu Kehidupan; M; METI - MZKromatografi; Senyawa Alami; Senyawa AlamiAnalisis KetrampilanAmalan . Tutup ... |
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File Mol: |
81-14-1.mol |
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Titik lebur |
135-139 ° C (surem) |
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Titik didih |
436.08 ° C (paling angel) |
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kapadhetan |
1.2051 (paling kasar) |
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indeks bias |
1.5110 (ngira) |
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Fp |
2 ° C |
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temp panyimpenan |
2-8 ° C |
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Kelarutan Banyu |
Ora larut (<0.1g / 100 mL ing 20 º C) |
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BRN |
2062638 |
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Stabilitas: |
Mantep Kompatibel karo agen oksidasi kuat, asam kuat, basa kuat. |
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InChIKey |
WXCMHFPAUCOJIG-UHFFFAOYSA-N |
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Referensi CAS DataBase |
81-14-1 (Referensi CAS DataBase) |
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Referensi Kimia NIST |
2,6-Dimethyl-3,5-dinitro-4-t-butylacetophenone (81-14-1) |
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Sistem Registrasi Bahan EPA |
Muskketone (81-14-1) |
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Kode Bahaya |
F, Xn, N |
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Pernyataan Risiko |
11-20 / 21 / 22-36-50 / 53-40 |
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Pernyataan Keamanan |
16-36 / 37-61-60-46 |
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RIDADR |
UN1648 3 / PG 2 |
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WGK Jerman |
2 |
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RTECS |
KM5775841 |
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Properti Kimia |
Powde kristal putih nganti entheng |
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Properti Kimia |
Wangun yellowishcrystals kanthi aroma kasturi sing kewan sing angel banget, terus-terusan, ketoneis musik sing disiapake dening Friedelâ € "Kerajinan asetilasi 1,3-dimethyl-5-tert-butylbenzeneand nitration saka 2,6- dimethyl-4-tert- butylacetophenone withnitric acid. |
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Katrangan Umum |
Yellowcrystalline cahya padhet. Ora larut ing banyu. |
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Reaksi Udhara & Banyu |
Ora larut ing banyu. |
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Profil Reaktivitas |
Keton nitrat. Keton reaktif karo akeh asam lan basa sing mbebasake panas lan flammablegases (kayata H2). Jumlah panas bisa uga cukup kanggo miwiti kobongan ing bagean keton sing ora digawe. Keton bereaksi karo agen pangurangan kayata hidrida, logam alkali, lan nitrida kanggo ngasilake gas sing gampang bakar (H2) lan panas. Keton ora cocog karo isokyanat, aldehid, sianida, peroksida, lan anhidrida. Dheweke reaksi kanthi parah karo aldehida, HNO3, HNO3 + H2O2, lanHClO4. |
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Bebaya Api |
Data titik kilat ora kasedhiya kanggo keton Musk, nanging, keton Musk bisa uga gampang diobong. |
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Metode Pemurnian |
Ngresiki byrecrystallisation keton saka MeOH. Iki duwe ambu ora enak kasturi lan digunakake kanggo inperfumery. [Fuson dkk. J Org Chem 12 587 1947, Beilstein 7 IV 808.] |
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Bahan baku |
Seng klorida -> Ferric klorida -> 2-Methyl-1-propanol -> m-Xylene -> 5-TERT-BUTYL-M-XYLENE -> 4'-tert-Butylacetophenone |
